Alcohol Losses & Recovery Estimation
technologist | 26 Jul, 2007, 05:17 | Energy | (388 Reads)
This is with reference to my previous log on this topic.
Background
Alcohol is stored in conventional storage tanks at site, which are non-insulated & low pressure fixed roof tanks. In this kind of storage system, there are three different types of losses of stored liquid.

1. WORKING LOSS

Losses due to displacement of inner air space during filling & evacuation. The material is lost each time during filling while fresh air intake results in additional evaporation inside the tank to maintain its partial pressure of liquid in vapor space.

2. BREATHING LOSS
Losses due to contraction and expansion of vapor space due to variation in day – night temperature. This also causes similar effect as explained above in item 1.

3. LOSSES DUE TO HEAT GAIN
Due to difference in ambient temperature & bulk liquid temperature, the material stored gets energy input through radiative & convective heat transfer from atmosphere. This is significant energy gain by the system compared to other two losses explained above.

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LCC Analysis
technologist | 26 Jul, 2007, 05:15 | General | (275 Reads)

Life-cycle cost analysis (LCCA) is a method for assessing the total cost of facility ownership. It takes into account all costs of acquiring, owning, and disposing of a project. LCCA is especially useful when project alternatives that fulfill the same performance requirements, but differ with respect to initial costs and operating costs, have to be compared in order to select the one that maximizes net savings.

For example, LCCA will help determine whether the incorporation of a good HVAC or glazing system, which may increase initial cost but result in dramatically reduced operating and maintenance costs, is cost-effective or not.

LCCA is not useful for budget allocation.

Lowest life-cycle cost (LCC) is the most straightforward and easy-to-interpret measure of economic evaluation. Some other commonly used measures are Net Savings (or Net Benefits), Savings-to-Investment Ratio (or Savings Benefit-to-Cost Ratio), Internal Rate of Return, and Payback Period. They are consistent with the Lowest LCC measure of evaluation if they use the same parameters and length of study period. The approach to making cost-effective choices for projects can be quite similar.

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Ways to save energy in pumps
technologist | 26 Jul, 2007, 05:13 | Energy | (343 Reads)

Here is my experience based on energy audits of pumping systems in various chemical, metal, textile & petrochemical units. Design systems with lower capacity and total head. Do not assume these requirements are fixed. Calculate flow requirement based on actual mathematical nos without margins in each stage & then add 10-20% straightforward as Normal capacity of the pump. For example if process side heat load in an exchanger is based on normal flow of say 100 M3/hr then do not consider cooling water requirement for peak condition of 120 or say 140 M3/hr. Just calculate it based on normal flow of 100 M3/hr at this stage. Total head requirements can be reduced by: lowering process static gage, pressure, minimizing elevation rise from suction tank to discharge tank, reducing static elevation change by use of siphons, lowering spray nozzle velocities, lowering friction losses through use of larger pipes and low-loss fittings, and eliminating throttle valves.

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Another use of Corn - PEG
technologist | 26 Jul, 2007, 05:11 | Technology | (287 Reads)
An industrial chemical found in antifreeze, de-icing fluids, and liquid detergents could soon stand alongside animal feeds, sweeteners and cooking oil as a commercial product made from corn.

Randy Cortright and James Dumesic, chemical engineers at the University of Wisconsin-Madison, have invented a catalytic process for converting the corn-derived compound, lactic acid, into the chemical polypropylene glycol. More than 450 MT of polypropylene glycol are used in the United States annually.

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Learnings from leakges in Phosphoric acid plant
technologist | 26 Jul, 2007, 05:09 | General | (228 Reads)

System Background In the concentrator section of phosphoric acid plant, weak phosphoric acid is concentrated by evaporation in graphite made evaporator. This is normally operated under vacuum & ~88°C temperature due to highly corrosive nature of phosphoric acid (PA). Over a period of time, the tubes of this exchanger require cleaning for removal of deposits & fouling material. This is a normal practice in both plants i.e. PAP-I & PAP-II.

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Useful tips for ASD / VFD Selection
technologist | 26 Jul, 2007, 05:08 | General | (225 Reads)

ASDs are ideally suited for variable-torque loads from centrifugal pumps, fans, and blowers when the system load requirements (head, flow, or both) vary with time. Conditions that tend to make ASDs cost-effective include the following: High horsepower (greater than 15 to 30 hp)—the higher the pump horsepower, the more cost-effective the ASD application. Load type—Centrifugal loads with variable-torque requirements (such as centrifugal pumps or fans) have the greatest potential for energy savings. ASDs can be cost-effective on positive displacement pumps, but the savings will generally not be as great as with centrifugal loads.

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Electricity from Waste water
technologist | 20 Jul, 2007, 02:27 | Technology | (207 Reads)

Researchers are studying the viability of creating electricity from microbes that are continuously fed with wastewater. If this technology reaches a proven and commercially realizable point, we could see a new edge technology in power generation.

Researchers from the University of Washington in St. Louis have been working on microbial fuel cell that generates electricity from wastewater. The science behind this technology is quite simple. Wastewater contains, among other things, organic matter. This organic matter can serve as a feedstock for many bacterial reactions.

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Water As Fuel
technologist | 20 Jul, 2007, 02:24 | Technology | (201 Reads)
Forget cars fuelled by alcohol and vegetable oil. Before long, you might be able to run your car with nothing more than water in its fuel tank. It would be the ultimate zero-emissions vehicle.
While water, plain old H2O, is not at first sight an obvious power source, it has a key virtue: it is an abundant source of hydrogen, the element widely touted as the green fuel of the future. If that hydrogen could be liberated on demand, it would overcome many of the obstacles that till now have prevented the dream of a hydrogen-powered car becoming reality. Producing hydrogen by conventional industrial means is expensive, inefficient and often polluting. Then there are the problems of storing and transporting hydrogen. The pressure tanks required to hold usable quantities of the fuel are heavy and cumbersome, which restricts the car's performance and range.

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Butanol Vs Ethanol Vs Future..............????
technologist | 20 Jul, 2007, 02:21 | Technology | (235 Reads)
Bio - Butanol

  • Can be made from natural sugar or starch including waste materials.
  • Costs less than ethanol.
  • Has 92% of the energy content of gasoline.
  • Mixes well with gasoline or ethanol.
  • Evaporates more slowly than either gasoline or ethanol.
  • Can be used in place of gasoline with no engine or fuel system changes.
  • Makes usable hydrogen as a by product.
  • Higher energy content (110,000 Btu’s per gallon for butanol vs. 84,000 Btu per gallon for ethanol). Gasoline contains about 115,000 Btu’s per gallon.

Read More....

 (More)
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China: Growing Fast
technologist | 20 Jul, 2007, 02:15 | General | (301 Reads)
By 2010 purchases of centrifugal pumps in China will rise to over $5 billion, surpassing the U.S., whose purchases are projected at under $4.9 billion. These are the latest forecasts in Pumps:

The top ten purchasers in 2010 will include primarily Asian and European countries:

2010 Projected Centrifugal Pump Purchases ($ Millions)
China: 5,149
United States: 4,886
Japan: 1,595
India: 1,092

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Reduce Losses from Storage Tanks
technologist | 20 Jul, 2007, 02:13 | General | (153 Reads)

Reduce Losses from Storage Tanks

Today I was reading a question regarding reduction in losses from large storage tanks for solvents. The existing system was having ~300 tanks at set pressure of 200 mmWC with vent condensers. 10°C chilled water is used for chilling in those vent condensers with vent setting of non condensable at 300 mmWC.

Few experts on the forum suggested that use 2-3°C chilled water to reduce the vent losses and properly size the condensers for improved heat transfer.

Any comment……………Before I proceed…….If U really have different things in mind let me know & I offer a job in technical services department of my company.
(This offer is for readers from India only for Chemical Engineering Graduates with 0 to 8 years experience)
I will post my solution which I have implemented here cost effectively on Monday on my main blog http://profmaster.blogspot.com
___________________________________________________________________
Disclaimer: I do not guarantee the job offer unless the candidate qualifies other parameters of selection procedure.

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Suction Vs Discharge Gas Flow
technologist | 17 Jul, 2007, 22:25 | General | (160 Reads)
Today I was reading a very interesting discussion on one of the famous forums at Cheresources.

This was really interesting. Newcomers should learn these useful things to avoid confusing states and hence it enables them for better decision making skills.


Why there is a difference in the measured suction flow & discharge flow of a blower (No Spill Back or antisurge or recycle is there). She got Suction flow as 62000 Nm3/Hr and discharge as 48000. How it is possible??????????

Read More......
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Energy Efficient Ethanol Production
technologist | 17 Jul, 2007, 22:18 | Technology | (163 Reads)

Chemical engineers Richard D. Offeman and George H. Robertson at the ARS Western Regional Research Center in Albany, Calif., think it may be possible to cut energy costs by using a series of specially designed permeable plastic sheets, or membranes, to produce ethanol from fermented broths of corn, or straw and other kinds of biomass feedstocks.

The technology will help to address the serious concern regarding the energy efficiency of bioethanol production, according to Robert L. Fireovid, ARS national program leader for process engineering and chemistry, Beltsville, Md.

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Carnot Cycle - An Insight
technologist | 07 Jul, 2007, 09:35 | Technology | (318 Reads)

This is in continuation of my previous article on 'Thermodynamics of Thermal Cycles' & is related to practical aspects of it.

All standard heat engines (steam, gasoline, diesel) work by supplying heat to a gas, the gas then expands in a cylinder and pushes a piston to do its work. The catch is that the heat and/or the gas must somehow then be dumped out of the cylinder to get ready for the next cycle.

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Surface Tension
technologist | 06 Jul, 2007, 23:26 | General | (222 Reads)

In the literature surface tensions of liquids are usually given at one temperature only (often 15 or 20 °C). As the temperature is raised, the surface tension decreases and becomes zero at the critical point. Based on this observation the surface tension at temperature T2 can be estimated for most liquids from the following simple equation if surface tension at another temperature T1 and critical temperature Tc of the liquid are known

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Cool it in.......... Summer
technologist | 06 Jul, 2007, 23:23 | Energy | (207 Reads)

Perfect tips for the Summer!



Cooling costs can chill your budget in the peak summer months। Here are few tips for chilling out without going broke:



  • Block out the sun. Using shades and blinds to block sunlight minimizes the amount of energy needed to cool your house. It's also worth noting that dark-colored exterior walls and roof tops can absorb up to 90% of the sun's radiant energy. To keep things cool, try painting your house a brighter color.

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Safeguard your Compressors
technologist | 06 Jul, 2007, 21:38 | General | (131 Reads)
Generally almost every industry face the problem of failures / corrosion / pitting in compressors internals due to presence of mainly mositure while handling any gas coming out through a wet system or air.
The Reason


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People can't be bothered to make easy energy savings
technologist | 05 Jul, 2007, 23:22 | Energy | (157 Reads)

According to Philips Lighting a standard incandescent light bulb costs around €1, and uses €15-worth of electricity a year. A low-energy one costs €5-6 and uses €3-worth. The payback on investing in a compact fluorescent bulb, therefore, is less than a year. Yet low-energy lighting makes up only 30% of Philips's sales.

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Tray Towers - Few Thumb Rules
technologist | 05 Jul, 2007, 23:14 | General | (136 Reads)
Tray Towers
  • For ideal mixtures, relative volatility can be taken as the ratio of pure component vapor pressures.
  • Tower operating pressure is most often determined by the cooling medium in condenser or the maximum allowable re-boiler temperature to avoid degradation of the process fluid.
  • For sequencing columns:

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Cooling Towers: Not the Coolest One
technologist | 05 Jul, 2007, 23:09 | Cooling Towers | (170 Reads)
This is the next one as I promised earlier in my first one "Cooling Towers: Not the Coolest One". This time I was motivated by the search of someone on cooling towers capacity assessment. I have already mentoned many factors & procedure to find out the capacity of cooling towers under the title Performance Monitoring - Item 9 to find out NTU. However, this search from some student led me to re-write it in simple way.
Let us understand how CT (cooling towers) capacity is fixed for design. (I am including this to give you an overview).
Read More...

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Compressed Air
technologist | 05 Jul, 2007, 01:29 | Energy | (366 Reads)
Compressed air is an essential part of any manufacturing / processing setup. It is treated as a simple air system without much attention to it, which finally appears as a slow eater of your profit & bottomline.
Compressed air is often overlooked in energy studies also even by experienced energy auditors because many people do not fully understand compressed air equipment, their own system, or what it costs to produce compressed air power. Here is a pie chart representing various cost areas.

Some Facts
For those who are willing to take a look, and utilize golden opportunity for saving,

For More....


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Packed Towers - Few Thumb Rules
technologist | 04 Jul, 2007, 23:12 | Technology | (144 Reads)
  1. Packed towers almost always have lower pressure drop than comparable tray towers.
  2. Packing is often retrofitted into existing tray towers, to increase capacity or separation. Thus same size of packed towers can handle more than tray towers.
  3. For gas flow rates of 500 ft3/min (14 m3/min) use 1 in (2.5 cm) packing, for gas flows of 2000 ft3/min (57 m3/min) or more, use 2 in (5 cm) packing.

Read More....


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Energy Saving Tips-2
technologist | 04 Jul, 2007, 01:12 | Energy | (169 Reads)
  1. In many cases you can use lower wattage bulbs and get same amount of light. Look for lumens on the bulb (CFL) & not for watts. Lumen indicates the brightness while power indicates eenrgy required to illuminate the area.
  2. Always plan bulb location in such a way that the light is not hindered by any other room fixture.
  3. White light is more comfortable than any other light for reading & day to day use. So should consider it in studies, drawing room etc. Other types can be considered for infrequently used areas e.g. toilet, bathroom etc.

Read More........


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Energy Saving Tips-1
technologist | 04 Jul, 2007, 01:09 | Energy | (175 Reads)
Tips in Day to Day Life
Refrigeration / Air Conditioning
"Hibernate or turn off computer while not in use". - Submitted by user 'Almk'.
  1. Select proper size AC based on room size, family members, wall & window area etc.
  2. Keep your refrigerator & freezers filled to capacity without restricting air circulation.
  3. Regularly clean the condenser parts of your refrigerator & AC both to have better efficiency without loosing energy.

Read More........


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Chaeper Solar Power
technologist | 04 Jul, 2007, 01:07 | Technology | (143 Reads)
Dr Wayne Campbell and researchers in the Massey University centre have developed a range of coloured dyes for use in dye-sensitised solar cells.

The synthetic dyes are made from simple organic compounds closely related to those found in nature. The green dye is synthetic chlorophyll derived from the light-harvesting pigment plants use for photosynthesis. Other dyes being tested in the cells are based on haemoglobin, the compound that give blood its colour.

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Common Eco-Myth: Sodium Lauryl Sulfate (SLS) Causes Cancer
technologist | 04 Jul, 2007, 01:05 | General | (127 Reads)

"One such misperception that has managed to persist in the public domain over the last few years is the perceived carcinogenic risk posed by sodium lauryl sulfate, a chemical commonly found in beauty care products. Despite strong evidence to the contrary, including an article published by the American Cancer Society definitively positing no link...

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180 Food Factories shut down for use of illegal chemicals
technologist | 04 Jul, 2007, 01:04 | General | (126 Reads)

This is happening in China today. This has happened in China as far as I know for at least 10-20+ years. I'm surprised that the media is only paying attention to this story now. I know it sounds rather paranoid, but it IS possible to avoid products 'Made in China'. Even towels made in China can expose a person to illegal chemicals!

Read More.....


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The longest chemical name, 64,060 letters
technologist | 04 Jul, 2007, 01:01 | General | (153 Reads)

Featured today in Wikipedia's newest pages, Methionylalanylthreonyl...leucine is a chemical name for enaptin, a nuclear envelope protein found in human myocytes and synapses, which is made up of 8,797 amino acids. Hope this won't be a dupe, this will be hard to search for.

Read Full Name........


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Engineers Find Way To Make Ethanol, Valuable Chemicals From Waste Glycerin
technologist | 02 Jul, 2007, 20:46 | Technology | (165 Reads)
With U.S. biodiesel production at an all-time high and a record number of new biodiesel plants under construction, the industry is facing an impending crisis over waste glycerin, the major byproduct of biodiesel production.
New findings from Rice University suggest a possible answer in the form of a bacterium that ferments glycerin and produces ethanol, another popular biofuel.

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Waste Heat Driven Engine
technologist | 02 Jul, 2007, 01:42 | Technology | (168 Reads)
Deluge, Inc. has developed a thermal hydraulic engine that is now ready for commercialization. The company has successfully completed long term field testing of the technology, and has obtained patents on the design in nearly 40 industrialized countries world wide.

The Natural Energy Engine™, requires no combustion, operates virtually silently, and generates no emissions. It operates by utilizing low level heat energy ~80°C suitable for many applications, from solar, geothermal, or any other heat source, including waste heat from existing processes.

The main components of the engine system are quite simple – a piston/cylinder and a heat transfer system. The cylinder contains a piston and a working fluid, and depending on the application may have a module to reposition the piston after each stroke. The heat transfer system comprises heat exchangers, a system to circulate the heat transfer fluid (typically water), and a simple circulation controller.

The key difference between a traditional combustion engine and the NE Engine is that the NE Engine relies on the transfer of heat to, and its subsequent removal from, a working fluid within the cylinder. As the working fluid is heated it expands, providing the pressure to drive the piston, and is subsequently cooled to complete the cycle.

The Company projects that engine configurations can easily be priced at 60-85% of power systems that produce equivalent output.

The NE Engine creates mechanical energy in a three step process:
Step 1: Heated water is collected – for many applications 80°C is suitable.

Step 2: The hot water enters a heat exchanger where the heat is transferred to a working fluid. The working fluid, typically liquefied CO2, has a very high coefficient of expansion, meaning that it expands and contracts significantly, based on its temperature, while remaining in a liquid state. As the working fluid is heated, it expands, pushing a piston in the engine’s cylinder.

Step 3: Cooling water – generally in the range of 100° F lower than the input water, with varying differentials depending on the application – then enters the heat exchanger causing the working fluid to contract, readying the piston for another stroke.

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Ammonia - Counting Energy
technologist | 02 Jul, 2007, 01:16 | Energy | (199 Reads)
The actual performance of any chemical process plant can be measured by only two terms, energy consumption level and on-stream/reliability factor. These are the two overall indicators of the plant performance out of which reliability factor also contributes to the energy consumption level. Hence, it becomes inevitable in an energy intensive unit like fertilizer industry, to keep a close look on this aspect of plant performance. This in turn will affect the productivity and profitability.


The expected annual energy consumption in ammonia production is of the order of 108 gigacalories in India alone that is equivalent to ~11 to 12000 MSm3 of Natural Gas or around 10 million tons of naphtha. Hence, it is most likely today to focus on proper analysis of bottlenecks & deficiencies in an existing plant while absolute analysis of technology at grass root level is also crucial with great care in its selection.


This study has been divided in four major parts, the overall loss structure, brief analysis of sectionwise losses & their remedies, losses through cooling water, and finally the role of catalysts in overall energy efficiency of the plant.

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Thermodynamics of Thermal Cycles
technologist | 01 Jul, 2007, 21:40 | General | (129 Reads)

A machine is a mechanical device with moving parts that helps to do some useful action, usually work. Machines may be just mechanical (pulley-and-belt), hydraulic (water wheel, the earliest engine), pneumatic (windmill), electrical (electric motor, the most common nowadays), chemical (fuel cell), or thermal.

I am restricting it to devices that converts heat to work (heat engine), and to devices that pump low-temperature energy to high-temperature energy (by using some source of exergy), all working cyclically. The heat-pumping machine may be intended to produce cold (refrigerator), or to produce heat (heat pump), or both at the same time (refrigerator with heat recovery, or heat pump).

Heat EnginesDefining it?

Want to read more......


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